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91.
Sophie Rihs Damien Lemarchand Marie-Claire Pierret François Chabaux 《Geochimica et cosmochimica acta》2011,75(23):7707-7724
The recent chemical dynamics of a podzolic forest soil section (from the Strengbach watershed, France) was investigated using U- and Th-series nuclides. Analyses of (238U), (230Th), (226Ra), (232Th), (228Ra) and (228Th) activities in the soil particles, the seepage waters, and the mature leaves of the beech trees growing on this soil were performed by TIMS or gamma spectrometry. The simultaneous analysis of the different soil (sl) compartments allows to demonstrate that a preferential Th leaching over Ra must be assumed to explain the (226Ra/230Th), (228Ra/232Th) and (228Th/228Ra) disequilibria recorded in the soil particles. The overall Ra- and Th- transfer schemes are entirely consistent with the prevailing acido-complexolysis weathering mechanism in podzols. Using a continuous open-system leaching model, the (226Ra/230Th) and (228Ra/232Th) disequilibria measured in the different soil layers enable dating of the contemporary processes occurring in this soil. In this way, we have determined that a preferential Th-leaching from the shallow Ah horizon, due to a strong complexation with organic colloids, began fairly recently (18 years ago at most). The continual increase in pH recorded in precipitations over the last 20 years is assumed to be the cause of this enhanced organic complexation. A lower soil horizon (50-60 cm) is also affected by preferential Th leaching, though lasting over several centuries at least, with a much smaller leaching rate. The migration of Th isotopes through this soil section might hence be used as a tracer for the organic colloids migration and the induced radioactive disequilibria demonstrate to be useful for assessing the colloidal migration kinetics in a forested soil.Ra and Th isotopic ratios also appear to be valuable tracers of some mineral-water-plant interactions occurring in soil. The (228Ra/226Ra) ratio enables discrimination of the Ra flux originating from leaf degradation from that originating from mineral weathering in shallow −10 cm seepage soil waters. It appears that, at least in some cases, the Ra-isotopic ratio measured in forest-soil seepage waters may not be representative of the Ra-isotopic ratio released from mineral weathering, indicating that the different origins of the dissolved 226Ra and 228Ra must be taken into account. 相似文献
92.
Dominique Genna Damien Gaboury Lyndsay Moore Wulf U. Mueller 《Journal of Geochemical Exploration》2011
A new analytical method using micro-X-ray fluorescence (XRF) is presented for the in situ analysis of major elements in rock samples. This approach has allowed for a separate study of hydrothermal alteration of matrix versus fragments in volcaniclastic material (i.e. flow breccia). This is particularly important for volcanogenic massive sulfide (VMS) exploration in subaqueous felsic dome-flow complexes, where brecciated facies are omnipresent and the imprint of hydrothermal alteration is typically heterogeneous. In this study, eleven elements are measured with a 1.7 by 1.3 mm window considered to be representative of each sample, based on replicate analyses. An average is calculated for the analyzed window and yields a nearly complete analysis with the exception of loss of ignition (LOI). Micro-XRF data were validated using whole rock XRF analyses performed on the same sample block. The application of this chemical method has been tested successfully on thin sections from the Cap d'Ours section of the Glenwood rhyolite in the Rouyn-Noranda region of Québec, Canada. With 58 samples spaced at approximately 50 m intervals, two styles of alteration zoning were recognized: (1) a lateral and concordant zoning expressed by vent-proximal silicification in the west grading toward vent-distal chlorite–sericite alteration to the east, and (2) vertical and discordant zoning expressed by stronger sericitization in the upper part of later volcanic quartz- and feldspar-phyric endogenous lobes. The former is typical of cooling induced by seawater interaction at the lava–water interface at temperatures greater than 400 °C, whereas the latter is related to lower temperature (< 300 °C) hydrothermal mineralization associated with endogenous lobe emplacement within the volcanic pile. The presented results clearly demonstrate the potential use of the micro-XRF data for characterizing weak to intense hydrothermal alteration in highly fragmented volcanic rocks. 相似文献
93.
François Chabaux Lin Ma Peter Stille Eric Pelt Mathieu Granet Damien Lemarchand Raphael di Chiara Roupert Susan L. Brantley 《Applied Geochemistry》2011
The development of U-series nuclides for investigating weathering processes has been significantly stimulated by the analytical improvement made over the last decades in measuring the 238U series with intermediate half-lives (i.e., 234U–230Th–226Ra). It is proposed in this paper to present principles and methods that are now being developed to determine weathering rates from the study of U-series nuclides in soils and weathering profiles. Mathematical approaches, developed to calculate such rates, are based on some implicit assumptions that are also presented and must be kept in mind if one wants to correctly interpret the obtained ages. 相似文献
94.
Damien Pas Anne-Christine Da Silva Thomas Suttner Erika Kido Pierre Bultynck Monica Pondrelli Carlo Corradini David De Vleeschouwer Claudia Dojen Frédéric Boulvain 《International Journal of Earth Sciences》2014,103(2):519-538
The development and behavior of million year-scaled depositional sequences recorded within Palaeozoic carbonate platform has remained poorly examined. Therefore, the understanding of palaeoenvironmental changes that occur in geological past is still limited. We herein undertake a multi-disciplinary approach (sedimentology, conodont biostratigraphy, magnetic susceptibility (MS), and geochemistry) of a long-term succession in the Carnic Alps, which offers new insights into the peculiar evolution of one of the best example of Palaeozoic carbonate platform in Europe. The Freikofel section, located in the central part of the Carnic Alps, represents an outstanding succession in a fore-reef setting, extending from the Latest Givetian (indet. falsiovalis conodont zones) to the Early Famennian (Lower crepida conodont zone). Sedimentological analysis allowed to propose a sedimentary model dominated by distal slope and fore-reef-slope deposits. The most distal setting is characterized by an autochthonous pelagic sedimentation showing local occurrence of thin-bedded turbiditic deposits. In the fore-reef slope, in a more proximal setting, there is an accumulation of various autochthonous and allochthonous fine- to coarse-grained sediments originated from the interplay of gravity-flow currents derived from the shallow-water and deepwater area. The temporal evolution of microfacies in the Freikofel section evolves in two main steps corresponding to the Freikofel (Unit 1) and the Pal (Unit 2) limestones. Distal slope to fore-reef lithologies and associate changes are from base to top of the section: (U1) thick bedded litho- and bioclastic breccia beds with local fining upward sequence and fine-grained mudstone intercalations corresponding, in the fore-reef setting, to the dismantlement of the Eifelian–Frasnian carbonate platform during the Early to Late Frasnian time (falsiovalis to rhenana superzones) with one of the causes being the Late Givetian major rift pulse; (U2) occurrence of thin-bedded red nodular and cephalopod-bearing limestones with local lithoclastic grainstone intercalations corresponding to a significant deepening of the area and the progressive withdrawal of sedimentary influxes toward the basin, in relation with Late Frasnian sea-level rise. MS and geochemical analyses were also performed along the Freikofel section and demonstrate the inherent parallel link existing between variation in MS values and proxy for terrestrial input. Interpretation of MS in terms of palaeoenvironmental processes reflects that even though distality remains the major parameter influencing MS values, carbonate production and water agitation also play an important role. 相似文献
95.
Fossils of megaherbivores from eight late Pleistocene 14C- and OSL-dated doline infillings of Ajoie (NW Switzerland) were discovered along the Transjurane highway in the Swiss Jura. Carbon and oxygen analyses of enamel were performed on forty-six teeth of large mammals (Equus germanicus, Mammuthus primigenius, Coelodonta antiquitatis, and Bison priscus), coming from one doline in Boncourt (~ 80 ka, marine oxygen isotope stage MIS5a) and seven in Courtedoux (51–27 ka, late MIS3), in order to reconstruct the paleoclimatic and paleoenvironmental conditions of the region. Similar enamel δ13C values for both periods, ranging from − 14.5 to − 9.2‰, indicate that the megaherbivores lived in a C3 plant-dominated environment. Enamel δ18OPO4 values range from 10.9 to 16.3‰ with a mean of 13.5 ± 1.0‰ (n = 46). Mean air temperatures (MATs) were inferred using species-specific δ18OPO4–δ18OH2O-calibrations for modern mammals and a present-day precipitation δ18OH2O-MAT relation for Switzerland. Similar average MATs of 6.6 ± 3.6°C for the deposits dated to ~ 80 ka and 6.5 ± 3.3°C for those dated to the interval 51–27 ka were estimated. This suggests that these mammals in the Ajoie area lived in mild periods of the late Pleistocene with MATs only about 2.5°C lower than modern-day temperatures. 相似文献
96.
Ionospheric delay corrections for single-frequency GPS receivers over Europe using tomographic mapping 总被引：3，自引：2，他引：1
The majority of navigation satellites receivers operate on a single frequency and experience a positioning error due to the
ionospheric delay. This can be compensated for using a variety of approaches that are compared in this paper. The study focuses
on the last solar maximum. A 4D tomographic imaging technique is used to map the ionospheric electron density over the European
region during 2002 and 2003. The electron density maps are then used to calculate the excess propagation delay on the L1 frequency
experienced by GPS receivers at selected locations across Europe. The excess delay is applied to correct the pseudo-range
single frequency observations at each location and the improvements to the resulting positioning are calculated. The real-time
tomographic technique is shown to give navigation solutions that are better than empirical modelling methods and approach
the accuracy of the full dual-frequency solution. The improvements in positioning accuracy vary from day to day depending
on ionospheric conditions but can be up to 25 m during mid-day during these solar maximum conditions at European mid-latitudes.
相似文献
| Damien J. AllainEmail: |
97.
Geordie Mark Damien R. W. Foster Peter J. Pollard Patrick J. Williams Justin Tolman Michael Darvall Kevin L. Blake 《地学学报》2004,16(2):54-61
Sodic–calcic alteration is common in mineralized hydrothermal systems, yet the relative importance of igneous vs. basinal fluid sources remains controversial. One of the most extensive volumes of sodic–calcic rocks occurs near Cloncurry, NW Queensland, and was formed by overlapping hydrothermal systems that were active synchronously with emplacement of mid‐crustal batholithic granitoids (c. 1.55–1.50 Ga). Altered rocks contain albite–oligoclase, actinolite, diopside, titanite and magnetite. Alteration was localized by: (A) composite veins and breccias containing crystallized magma intimately intergrown with hydrothermal precipitates; (B) intrusions that host setting A veins and breccias; and (C) extensive breccia and vein systems linked to regional fault systems. Isotope analyses of actinolites in settings A and B indicate calculated δ18OH2O (+8.2 to +10.6‰) and variably depleted δDH2O (?130 to ?54‰) compared with typical magmatic fluids, whereas those from setting C typically indicate calculated δ18OH2O (+8.0 to +12.8‰) and δDH2O (?29 to ?99‰). The lowest δDH2O values are interpreted as representing residual fluids after significant (> 90%) open‐system magmatic degassing. Overall the stable isotope, field, geochronological and geobarometric data suggest that these sodic–calcic alteration systems were formed by the episodic incursion of magmatic fluids that underwent minor isotopic modification as a result of varying degrees of interaction with country rocks. 相似文献
98.
Neogene tectonostratigraphic history of the southern Neuquén basin (39°–40°30′S,Argentina): implications for foreland basin evolution 
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下载免费PDF全文 Damien Huyghe Cédric Bonnel Bertrand Nivière Bertrand Fasentieux Yves Hervouët 《Basin Research》2015,27(5):613-635
Although the Neuquén basin in Argentina forms a key transitional domain between the south‐central Andes and the Patagonian Andes, its Cenozoic history is poorly documented. We focus on the sedimentologic and tectonic evolution of the southern part of this basin, at 39–40°30′S, based on study of 14 sedimentary sections. We provide evidence that this basin underwent alternating erosion and deposition of reworked volcaniclastic material in continental and fluvial settings during the Neogene. In particular, basement uplift of the Sañico Massif, due to Late Miocene–Pliocene intensification of tectonic activity, led to sediment partitioning in the basin. During this interval, sedimentation was restricted to the internal domain and the Collon Cura basin evolved towards an endorheic intermontane basin. From stratigraphic interpretation, this basin remained isolated 7–11 Myr. Nevertheless, ephemeral gateways seem to have existed, because we observe a thin succession downstream of the Sañico Massif contemporaneous with the Collon Cura basin‐fill sequence. Comparisons of stratigraphic, paleoenvironmental and tectonic features of the southern Neuquén basin with other foreland basins of South America allow us to classify it as a broken foreland with the development of an intermontane basin from Late Miocene to Late Pliocene. This implies a thick‐skinned structural style for this basin, with reactivation of basement faults responsible for exhumation of the Sañico Massif. Comparison of several broken forelands of South America allows us to propose two categories of intermontane basins according to their structural setting: subsiding or uplifted basins, which has strong implications on their excavation histories. 相似文献
99.
Christophe Grenier Damien Régnier Emmanuel Mouche Hakim Benabderrahmane François Costard Philippe Davy 《Hydrogeology Journal》2013,21(1):257-270
The impact of glaciation cycles on groundwater flow was studied within the framework of nuclear waste storage in underground geological formations. The eastern section of the Paris Basin (a layered aquifer with impervious/pervious alternations) in France was considered for the last 120 ka. Cold periods corresponded with arid climates. The issue of talik development below water bodies was addressed. These unfrozen zones can maintain open pathways for aquifer recharge. Transient thermal evolution was simulated on a small-scale generic unit of the landscape including a “river” and “plain”. Coupled thermo-hydraulic modeling and simplified conductive heat transfer were considered for a broad range of scenarios. The results showed that when considering the current limited river dimensions and purely conductive heat transfer, taliks are expected to close within a few centuries. However, including coupled advection for flows from the river to the plain (probably pertinent for the eastern Paris Basin aquifer recharge zones) strongly delays talik closure (millennium scale). The impact on regional underground flows is expected to vary from a complete stop of recharge to a reduced recharge, corresponding to the talik zones. Consequences for future modeling approaches of the Paris Basin are discussed. 相似文献
100.
Laura Torres-Rondon Simon Damien Carrière Konstantinos Chalikakis Vincent Valles 《Comptes Rendus Geoscience》2013,345(5-6):241-250
Deltaic aquifers are complex due to the important heterogeneity of their structure and their hydrogeological functioning. Auger drilling provides localized, but very robust geological and hydrogeological information, while geophysical surveys can provide integrated subsurface information. An effective, easy-to-use and low-cost methodology combining geological/hydrogeological information from Auger drillings and the results from three geophysical techniques (Electromagnetic mapping, Electrical Sounding and Electrical Resistivity Tomography) is being developed to characterize the structure of a typical Mediterranean deltaic aquifer. A first hypothesis about hydrodynamic properties of the aquifer is also obtained. The study area is located in the Rhone delta (Middle Camargue/southern France). Integration of geophysical and geological techniques allowed identifying the presence and lateral extension of the Saint-Ferréol paleochannel, the vertical contact between lagoonal–fluvial deposits and the marine clayed silt that separate the superficial aquifer from the deeper aquifer. Likewise, high north–south heterogeneity and east–west homogeneity were highlighted in the study area. Presence of clay in sandy deposits in the low areas implies changes in lateral hydraulic permeability. This fact, jointed to the low hydraulic gradient, suggests a slow groundwater flow in the local system. The Rhone delta presents a typical configuration of a Mediterranean deltaic aquifer, thus this methodological approach can be used for similar deltaic Mediterranean systems. 相似文献